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1 article(s) from Conte, Maxwell

Benzoimidazolium-derived dimeric and hydride n-dopants for organic electron-transport materials: impact of substitution on structures, electrochemistry, and reactivity

Swagat K. Mohapatra,
Khaled Al Kurdi,
Samik Jhulki,
Georgii Bogdanov,
John Bacsa,
Maxwell Conte,
Tatiana V. Timofeeva,
Seth R. Marder and
Stephen Barlow

Beilstein J. Org. Chem. 2023, 19, 1651–1663, doi:10.3762/bjoc.19.121

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Figure 1: DMBI⁺, DMBI-H, and (DMBI)₂ derivatives discussed in this work (new compounds in red).

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Scheme 1: Synthesis of DMBI-H and (DMBI)₂ derivatives and structures of side products.

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Figure 2: Crystallographically characterized molecules related to DMBI dimers.

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Figure 3: Molecular structures from the single crystal structures of 1b₂ (two crystallographically inequivale...

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Figure 4: Molecular structures from the single crystal structures of 1bH (upper left), 1gH (upper right), 1hH...

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Figure 5: Structures of the cations from the single crystal structures of 1g⁺I⁻ (left), 1h⁺PF₆⁻ (center), and ...

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Figure 6: Cyclic voltammograms (50 mV s⁻¹, THF, 0.1 M Bu₄NPF₆) of 1g⁺PF₆^–, 1gH, and 1g₂, in each case contain...

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Figure 7: Acceptors used to examine reactivity of DMBI-H and (DMBI)₂ derivatives.

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Figure 8: a) Temporal evolution of the absorbance at 1030 nm, corresponding to an absorption maximum of VI^•–,...

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Published 01 Nov 2023

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